Have you tried to push the valves down by the palm of your hands and see if the valve springs on number 6 physically feels a bit weaker. ? At TDC number 6 compression stroke, if you can spin the push rods easy with your finger tips I wouldn't think they would be riding enough to cause the exhaust valve leakage past the seat.
Now you know the problem is on number 6 cylinder a few more easy checks should identify the problem. If the popping stop when you remove either the spark plug spark of remove the fuel on no number 6, and the spark plug is black (indicating rich mixture) the issue might be the extra cylinder pressure escaping past the exhaust valve when partially ignited popping into the exhaust tract. possible but more unlikely due to having good compression.
If the spark plug is black its not burning all of the fuel and has a rich mixture, If you can read the information on your ecu, the o2 sensor will show a very rich mixture. I had 7 stuck (closed) fuel injectors when I went to start the VR engine in the SLR for the first time. Took me a while to find that one. Maybe your number 6 fuel injector is stuck open and flooding number 6. swap it to another cylinder will quickly tell you if this is the case. Or squirt 40-50 PSI air pressure through the removed injector and check if air passes through the injector. Suggestion number 3 the spark is firing at the incorrect time. Not sure what your using as a triggering device but maybe a problem with the trigger timing on number 6 only. I had a problem with a V6 Holden the harmonic balance trigger plate has a bit missing on the problem cylinder. To confirm a problem with number 6, use a timing light hooked up to number 6 spark plug lead and see how many degrees on the harmonic balance it firing at, if its after top dead centre there's your problem and the mixture is still trying to burn as the exhaust valve starts to open. Last check is the configuration of the ecu on number 6. don't know what program your running but maybe a timing offset on number 6 has been set incorrectly of something simple like the firing order set ect. I would probably check all cylinders spark plug timing and see where they are all firing as a starting point.
I reckon if you do the above checks you will find the problem.